Droplet formation in an ultracold gas of NaCs molecules with non-axially symmetric dipolar interactions.
Droplet formation in an ultracold gas of NaCs molecules with non-axially symmetric dipolar interactions.

Researchers create quantum liquid from ultracold molecules for the first time

Researchers from Radboud University and Columbia University (US) have for the first time created droplets of ultracold molecules. This is a new form of quantum matter in which particles interact so strongly that they spontaneously come together without any external force. The dipolar interaction between the molecules causes the droplets to self-organise into ordered patterns. The results have been published in Nature.

To create these droplets, the researchers cooled molecules to nanokelvin temperatures, just one billionth of a degree above absolute zero. Under these conditions, quantum effects dominate and the molecules behave collectively, forming a Bose-Einstein condensate in which many molecules share the same quantum state.

Controlling interactions

Until recently, researchers had only managed to create a Bose-Einstein condensate with atoms. With molecules, this proved impossible for a long time. The problem: when two molecules collide, they both disappear from the system, effectively undergoing a chemical reaction with each other.
'We have learned to switch off these losses', says Tijs Karman, researcher at Radboud University. Molecules have a dipole moment, which causes them to behave like tiny magnets. Using microwaves, these magnets can be controlled so that they all rotate synchronously. This can be done such that molecules that come too close repel each other instead of colliding. 'We essentially create a small shield around the molecules,' Karman explains.

In earlier research, the researchers kept that repulsion in balance so that the molecules influenced each other as little as possible. This produced a weakly interacting quantum gas: stable, but with little interaction between the molecules. Karman: 'In this new research, we deliberately break that balance. Using the same microwaves, we essentially turn a knob to increase the attractive force between the molecules.'

Droplet formation in an ultracold gas of NaCs molecules with non-axially symmetric dipolar interactions.

Image: Absorption images of a single droplet (left), a weakly dipolar BEC (middle) and a 1D droplet array (right) after 25-ms time-of-flight expansion. Each image is an average of three individual shots taken along the z direction. Black ellipses (bottom) indicate the trace of the electric field vector of the σ-field. Scale bar, 30 μm.

From quantum gas to quantum liquid

By controlling the polarisation of the microwaves, the researchers control how strongly the molecules attract each other. That long-range attractive force causes the molecules to come together into droplets that are self-bound and do not expand. The droplet is a hundred times denser than the original quantum gas. Because the molecules are packed so closely together, they interact strongly with one another, giving rise to a quantum liquid.

Better understanding of quantum materials

These strongly interacting quantum liquids provide a new platform for exploring many-body quantum physics and could help scientists better understand quantum materials. The complete control over tunable interactions between molecules that is achieved in this “artificial quantum material", is normally not possible in real materials.

Literature reference

Article information: Zhang, S., Yuan, W., Bigagli, N. et al. Observation of self-bound droplets of ultracold dipolar molecules. Nature 651, 601–606 (2026). https://doi.org/10.1038/s41586-026-10245-9

Contact information

For further information, please contact the researcher involved or team Science communication via +31 24 361 6000 or media [at] ru.nl (media[at]ru[dot]nl).   

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Molecules and materials