NWI-SM044A
Magnetic Resonance IIIb: solid-state NMR
Cursus informatieRooster
CursusNWI-SM044A
Studiepunten (ECTS)3
CategorieMA (Master)
VoertaalEngels
Aangeboden doorRadboud Universiteit; Faculteit der Natuurwetenschappen, Wiskunde en Informatica; Moleculaire Wetenschappen;
Docenten
Coördinator
prof. dr. A.P.M. Kentgens
Overige cursussen docent
Docent
prof. dr. A.P.M. Kentgens
Overige cursussen docent
Contactpersoon van de cursus
prof. dr. A.P.M. Kentgens
Overige cursussen docent
Examinator
prof. dr. A.P.M. Kentgens
Overige cursussen docent
Collegejaar2022
Periode
KW4  (10-04-2023 t/m 31-08-2023)
Aanvangsblok
KW4
Onderwijsvorm
voltijd
Opmerking-
Inschrijven via OSIRISJa
Inschrijven voor bijvakkersJa
VoorinschrijvingNee
WachtlijstNee
Plaatsingsprocedure-
Cursusdoelen
After completing this course the student:
  • has an in-depth theoretical knowledge of advanced solid-state NMR as applied in contemporary materials science
  • is able to predict the outcome of complex experiments from first principles and knows when to resort to numerical simulations to fully describe the spectra and extract all meaningful interaction parameters
  • is capable of chosing the right approach to eliminate or enhance specific NMR interactions and is aware of the field of application of these techniques
Inhoud
Based on the knowledge acquired in the courses Magnetic Resonance I and II, this course will give an in-depth treatment of a number of experiments which are at the heart of Solid State NMR and its applications in materials science and the study of bio(mimicking) materials. Themes will be:
  • The nuclear spin Hamiltonian (in spherical tensors operators) and its spectral manifestation in single crystals and powders; homogeneous vs. inhomogeneous line broadening.
  • Manipulation of spin Hamiltonians in real and spin space (sample spinning and multiple pulse techniques); Average Hamiltonian Theory.
  • Study of molecular motions; line narrowing; multidimensional exchange spectroscopy.
  • Double resonance; Cross-Polarization, SEDOR, REDOR.
  • Homo- and heteronuclear correlation spectroscopy; recoupling of dipolar interactions under Magic Angle Spinning.
  • Getting isotropic spectra for quadrupolar nuclei; DOR, DAS, MQMAS, STMAS.
  • Extracting information from spinning powders; Herzfeld and Berger analysis.
  • Hyperpolarization methods for sensitivity enhancement.
  • Simulation of advanced NMR experiments using the SIMPSON software.
Instructional Modes
Niveau

Voorkennis
Magnetic Resonance II (SM023D)
Toetsinformatie
Final Report on the theory, simulation and experimental implementation of a specific class of experiments
Bijzonderheden
In view of the small number of participants, scheduling of this course will take place in mutual consultation between lecturer and students.
Verplicht materiaal
Artikelen
Relevant Research Papers and notes on various solid-state NMR topics are handed out during the course.

Aanbevolen materiaal
Boek
This book is intended to provide the necessary background to those wishing to solve problems in chemistry, biochemistry, materials, geology and engineering.
Titel:Introduction to solid-state NMR spectroscopy
Auteur:M. Duer
Uitgever:Blackwell Publishing
Boek
Solid State NMR: Principles, Methods, and Applications offers a systematic introduction to the theory, methodological concepts, and major experimental methods of SSNMR spectroscopy. Exploring the unique potential of SSNMR for the structural and dynamic characterization of soft and either amorphous or crystalline solid materials, this comprehensive textbook provides foundational knowledge and recent developments of SSNMR, covering physical and theoretical background, experimental methods, and applications to pharmaceuticals, polymers, inorganic and hybrid materials, liquid crystals, and model membranes.
ISBN:978-3-527-31816-2
Titel:Solid State NMR: Principles, Methods, and Applications
Auteur:Klaus Müller, Marco Geppi
Uitgever:Wiley

Werkvormen
Cursus
AanwezigheidsplichtJa

Toetsen
Eindverslag
Weging1
ToetsvormWerkstuk
GelegenhedenBlok KW4, Blok KW4